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  Home >> Reagents >> BOOST >> PISA (CAS:2135323-39-4/5g)

Brand:BOOST
Item#:12050401404502
Score:315  (Score change Discount Voucher)
Weight:5 kg.
Name:(Phenyliodonio)sulfamate
CAS:2135323-39-4
RMW:299.0825
Decomp. Temp.(°C):117℃
W. Sol.:Soluble in water
N. W.:5g
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A series of indoles could be synthesized with excellent regioselectivity with PISA and 2-alkenylanilines. In this reaction, PISA acted both as an oxidant and as a Brønsted acid.

 

References:

Xia, H.; Zhang, Y.; Wang, Y.; Zhang, C. Water-Soluble Hypervalent Iodine(III) Having an I-N Bond. A Reagent for the Synthesis of Indoles. Org. Lett. 2018, 20, 4052-4056.

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